High-Temperature Study of Perovskite Evaporation

被引：1
作者：
Shornikov, Sergey [1 ]
机构：
[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow, Russia
来源：
MATERIALS PROCESSING FUNDAMENTALS 2019 | 2019年
关键词：
Knudsen effusion mass spectrometry; Thermodynamics of evaporation; Perovskite; SYSTEM; MELTS; VAPORIZATION; EQUILIBRIA; INCLUSIONS; CALCIUM; ENERGY; PHASE;
D O I：
10.1007/978-3-030-05728-2_23
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Evaporation of perovskitewas studied by high-temperatureKnudsen effusion mass spectrometric method at 1700-2200 K. Vapor species typical for simple oxides and a small amount of CaTiO3 complex gaseous oxide were identified in the gas phase over perovskite. For the first time, the partial pressure of vapor species in the gas phase over perovskite are compared with those corresponding to simple oxides, showing the predominant effect of the calcium component of perovskite on evaporation character.
引用
收藏
页码：253 / 263
页数：11
相关论文
共 26 条
[11]  
KOMLEV GA, 1964, ZH FIZ KHIM+, V38, P2747
[12]   Thermochemical study of gaseous salts of oxygen-containing acids: XI. Alkaline-earth metal titanates [J].
Lopatin, SI ;
Semenov, GA .
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (10) :1522-1526
[13]  
Ostrovski O, 2000, HIGH TEMP MATER PROC, V19, P345
[14]  
Samoilova I. O., 1995, RUSS METALL+, V1, P33
[15]  
Semenov GA, 1969, RUSS INORG MAT, V5, P67
[16]   Vaporization Coefficients of Oxides Contained in the Melts of Ca-Al-Inclusions in Chondrites [J].
Shornikov, S. I. .
GEOCHEMISTRY INTERNATIONAL, 2015, 53 (12) :1080-1089
[17]   Study of Complex Molecular Species in the Gas Phase over the CaO-MgO-Al2O3-TiO2-SiO2 System [J].
Shornikov, S. I. ;
Yakovlev, O. I. .
GEOCHEMISTRY INTERNATIONAL, 2015, 53 (08) :690-699
[18]  
Shornikov S. I., 1993, THESIS
[19]  
Shornikov S. I., 2000, P 9 WORLD C TIT PROM, V3, P1469
[20]  
Shornikov SI, 2000, RUSS J PHYS CHEM+, V74, P677
123