Successive Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Diblock Copolymers of Aromatic Polyamide and Aromatic Polyether

被引：11

作者：

Yokoyama, Akihiro ^{[1
]}

Masukawa, Tomohiro ^{[1
]}

Yamazaki, Yuka ^{[1
]}

Yokozawa, Tsutomu ^{[1
]}

机构：

[1] Kanagawa Univ, Dept Mat & Life Chem, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 01期

关键词：

chain-growth polymerization; condensation polymerization; diblock copolymers; polyamides; polyethers; LOW POLYDISPERSITIES; BLOCK-COPOLYMERS; POLYCONDENSATION; NANOSTRUCTURES; INTERPLAY; SOLVENT;

D O I：

10.1002/marc.200800546

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-defined diblock condensation copolymers composed of an aromatic polyamide and an aromatic polyether have been synthesized by means of successive chain-growth condensation polymerizations. Polymerization of a polyamide monomer with an orthogonally difunctional initiator is accompanied with side reactions. On the other hand, polymerization with a monofunctional initiator afforded well-defined polyamide, which has been converted into a macroinitiator by introduction of a terminal 4-fluorobenzophenone unit. Well-defined diblock copolymers are obtained by polymerization of a polyether monomer in the presence of this macroinitiator.

引用

页码：24 / 28

页数：5

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