Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption

被引：31

作者：

Jiang, Xiao-Ming ^{[1
]}

Wang, Guan-E ^{[1
]}

Liu, Zhi-Fa ^{[1
]}

Zhang, Ming-Jian ^{[1
]}

Guo, Guo-Cong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 15期

关键词：

2ND-HARMONIC GENERATION RESPONSE; CRYSTAL-STRUCTURE; BAND-STRUCTURES; CHEMISTRY; GROWTH; PHASE; RB; THRESHOLD; COMPLEXES; AGGAS2;

D O I：

10.1021/ic401056t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new different-bond-type hybrid compounds, (Hg6P4Cl3)(PbCl3) (1) and (Hg23P12)(ZnCl4)(6) (2), with supramolecular interactions between host and guest moieties, which based on metal pnicogen, pnicogen-pnicogen, and metal-halogen bonds were obtained by solidstate reactions. Compounds 1 and 2 show large secondharmonic-generation (SHG) activity and are transparent in the wide mid-IR region, providing an effective route for searching new IR nonlinear-optical material systems by combining two or more different bond types with no IR absorption within a single compound through supramolecular assembly. Theory predications based on first-principles calculations are also performed on the SHG properties of 1 and 2.

引用

页码：8865 / 8871

页数：7

共 5 条

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