Supramolecular polymerization in water harnessing both hydrophobic effects and hydrogen bond formation

被引:162
作者
Leenders, Christianus M. A. [1 ]
Albertazzi, Lorenzo [1 ]
Mes, Tristan [1 ]
Koenigs, Marcel M. E. [1 ]
Palmans, Anja R. A. [1 ]
Meijer, E. W. [1 ]
机构
[1] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands
关键词
POLYMERS; ASSEMBLIES; BEHAVIOR;
D O I
10.1039/c3cc38949a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The formation of supramolecular polymers in water through rational design of a benzene-1,3,5-tricarboxamide (BTA) motif is presented. Intermolecular hydrogen bonding and hydrophobic effects cooperate in the self-assembly into long fibrillar aggregates. Minimal changes in molecular structure significantly affect the internal packing of the aggregates.
引用
收藏
页码:1963 / 1965
页数:3
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