Europium Pyrimidine-4,6-dicarboxylate Framework with a Single-Crystal-to-Single-Crystal Transition and a Reversible Dehydration/Rehydration Process

被引：34
|
作者：
Sun, Hao-Ling [1 ,2 ]
Yin, Dan-Dan [1 ,2 ]
Chen, Qi [1 ,2 ]
Wang, Zhenqiang [3 ]
机构：
[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[2] Beijing Normal Univ, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China
[3] Univ S Dakota, Dept Chem, Vermillion, SD 57069 USA
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 07期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; TRANSFORMATION; SERIES; DEHYDRATION; LIGANDS;
D O I：
10.1021/ic302556r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this paper, a novel three-dimensional (3D) porous lanthanide-organic framework, Eu-2(mu(4)-pmdc)(2)(OH)(2)center dot 3H(2)O (1), which is stable up to 400 degrees C, has been hydrothermally synthesized and characterized. It shows intriguing single-crystal-to-single-crystal transformation and reversible dehydration/rehydration phenomenon upon removal and rebinding of the lattice water molecules, which is supported by single-crystal X-ray diffraction, powder X-ray diffraction, and photoluminescence data.
引用
收藏
页码：3582 / 3584
页数：3
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