Synthesis of ferrocene indanone derivatives via trinuclear N-heterocyclic carbene palladium(II)-catalyzed cyclocarbonylation of o-bromoarylferrocene

被引：5

作者：

Wang, Tao ^{[1
]}

Wang, Renjie ^{[2
]}

Wang, Wanli ^{[1
]}

Zhang, An'an ^{[1
]}

Liu, Lantao ^{[1
]}

机构：

[1] Shangqiu Normal Univ, Sch Chem & Chem Engn, Henan Engn Lab Green Synth Pharmaceut, Shangqiu 476000, Henan, Peoples R China

[2] Zhoukou Normal Univ, Sch Chem & Chem Engn, Zhoukou 466001, Henan, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 858卷

关键词：

Ferrocene indanone derivatives; Trinuclear N-heterocyclic carbene palladium; Carbonylative; PALLADIUM-CATALYZED CYCLOCARBONYLATION; PLANAR CHIRAL FERROCENES; ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE SYNTHESIS; COMPLEXES; FLUOREN-9-ONES; HALOBIARYLS; COUPLINGS; ARYLATION; LIGANDS;

D O I：

10.1016/j.jorganchem.2018.01.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route to ferrocene indanone derivatives has been developed via the trinuclear N-heterocyclic carbene palladium(II)-catalyzed carbonylative C-C bond formation. Under a CO atmosphere, using o-bromoarylferrocene as substrate, this reaction proceeded smoothly to give the desired products in moderate to excellent yields within hours. (c) 2018 Elsevier B.V. All rights reserved.

引用

页码：62 / 66

页数：5

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