One-pot production of hydrocarbon oils from biomass derived γ-valerolactone

被引：12

作者：

Kang, Shimin ^{[1
]}

Fu, Jinxia ^{[2
]}

Ye, Yueyuan ^{[3
]}

Liao, Wenbo ^{[1
]}

Xiao, Yukui ^{[1
]}

Yang, Pingju ^{[1
]}

Liu, Guiheng ^{[1
]}

机构：

[1] Dongguan Univ Technol, Guangdong Prov Key Lab Distributed Energy Syst, Dongguan, Guangdong, Peoples R China

[2] Univ Hawaii, Hawaii Nat Energy Inst, Honolulu, HI 96822 USA

[3] Xiamen Univ, Coll Energy, Xiamen, Peoples R China

来源：

FUEL | 2018年 / 216卷

基金：

中国国家自然科学基金;

关键词：

gamma-Valerolactone; Hydrocarbon oil; Deoxygenation; Phosphoric acid catalyst; GASOLINE; ACID;

D O I：

10.1016/j.fuel.2017.12.062

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Catalytic reforming reaction of gamma-valerolactone (GVL) derived from renewable cellulosic biomass was conducted to produce hydrocarbon oils using a phosphoric acid catalyst under mild temperature (240 degrees C). Excellent catalytic performance (over 99% conversion of GVL, 33.5 wt% yield of hydrocarbon oils) was achieved in a one-step reaction without external source of hydrogen. The hydrocarbon oil formed was rich in aromatics and had similar C/H ratio and higher heating value (HHV) in comparison with oxygenated commercial gasoline.

引用

页码：747 / 751

页数：5

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