Densities and Viscosities of 1-Butyl-3-methylimidazolium Trifluoromethanesulfonate + H2O Binary Mixtures at T = (303.15 to 343.15) K

被引:78
作者
Ge, Ming-Lan [1 ]
Zhao, Ru-Song [1 ]
Yi, Yu-Feng [1 ]
Zhang, Qi [1 ]
Wang, Li-Sheng [2 ]
机构
[1] Beijing Inst Petrochem Technol, Dept Chem Engn, Beijing 102617, Peoples R China
[2] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
关键词
D O I
10.1021/je8003832
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities for the binary mixtures of H2O (1) + 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF3SO3]) (2) were measured over the entire mole fraction range from (303.15 to 343.15) K at atmospheric pressure. Excess molar volumes and viscosity deviations as a function of mole fraction average were derived, and the results were fitted to the Redlich-Kister equation using a multiparametric nonlinear regression method. Estimated coefficients of the Redlich-Kister equation and standard error calculated from the Redlich-Kister equation to the experimental data are also presented. The results show that the densities and viscosities are dependent on water content and temperature.
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收藏
页码:2408 / 2411
页数:4
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