Synthesis of Meso-Halogenated BODIPYs and Access to Meso-Substituted Analogues

被引：118

作者：

Leen, Volker ^{[1
]}

Yuan, Peijia ^{[1
]}

Wang, Lina ^{[1
]}

Boens, Noel ^{[1
]}

Dehaen, Wim ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 24期

关键词：

DYES; 4,4-DIFLUORO-4-BORA-3A; DERIVATIVES; CHEMISTRY;

D O I：

10.1021/ol3028225

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

8-Halogenated boradiaza-s-indacenes can be efficiently prepared from dipyrrylketones. The new dyes react smoothly with nucleophiles to yield N-, O-, and S-substituted chromophores, as well as transition-metal-catalyzed cross-coupling reactions. The nature of the new substitutent has a strong influence on the spectral properties of the dyes.

引用

页码：6150 / 6153

页数：4

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