Direct synthesis and properties of binuclear copper(II) complexes

被引：0

作者：

Yang, RN ^{[1
]}

Wang, DM

Kuang, AY

Liu, YF

Jin, DM

机构：

[1] Henan Inst Chem, Zhengzhou 450002, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2001年 / 31卷 / 09期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1081/SIM-100107710

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

At room temperature, dibenzoyl peroxide undergoes an oxidative addition reaction with metallic copper powder and the relevant ligands afford binuclear copper(Il) complexes, [CU(OOCC6H5)(2)L](2), L=pyridine-2,6-dicarboxylic acid (L-1), THF (L-2), 3-aminopyridine (L-3), 4-aminopyridine (L-4), 2-methylpyridine (L-5), 2,6-dimethylpyridine (L-6) and 2-aminothiazol (L-7). These complexes were further characterized by physico-chemical and spectroscopic methods. The structure of complex (7) has been determined by a single-crystal X-ray analysis. Each copper(II) ion is coordinated by two bridging bidentate benzoates and one L (as defined above) ligand to form dimeric binuclear molecules.

引用

页码：1647 / 1662

页数：16

共 12 条

[1]

COLLMAN JP, 1980, PRINCIPLES APPL ORGA, P176

[2]

HU J, 1995, CHEM J CHINESE U, V16, P748

[3] A NOVEL SYNTHETIC METHOD FOR AND THE STRUCTURE OF TETRAKIS(MU-BENZOATO-O-O')-BIS(TRIPHENYLPHOSPHINE OXIDE)DICOPPER(II) - OXIDATIVE ADDITION OF DIBENZOYLPEROXIDE TO METALLIC COPPER [J].