A novel non-metathetic behavior of Grubbs catalyst: Ruthenium-mediated intramolecular [3+2] cycloaddition of bis-1,3-dienes

被引：9

作者：

Takagi, Ryukichi ^{[1
]}

Yamamoto, Koumei ^{[1
]}

Hiraga, Yoshikazu ^{[1
]}

Kojima, Satoshi ^{[1
]}

Abe, Manabu ^{[1
]}

机构：

[1] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 723卷

关键词：

Grubbs catalyst; Non-metathetic reaction; Ruthenium-mediated reaction; Intramolecular [3+2] cycloaddition; Bis-1,3-dienes; FISCHER CARBENE COMPLEXES; OLEFIN CROSS-METATHESIS; CLOSING METATHESIS; ORGANIC-SYNTHESIS; VIC-DIOLS; TANDEM; CLEAVAGE; TRANSFORMATIONS; POLYMERIZATION; DERIVATIVES;

D O I：

10.1016/j.jorganchem.2012.09.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A ruthenium-mediated intramolecular [3 + 2] cycloaddition of bis-1,3-dienes to give bicyclic products, which is a novel non-metathetic behavior of Grubbs catalyst, is reported. The formation of a ruthenium-olefin complex is proposed to be a key step for the success of the reaction. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：171 / 175

页数：5

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