Model for radiolysis of water and aqueous solutions of H2, H2O2 and O2

被引：89
|
作者：
Ershov, B. G. [1 ]
Gordeev, A. V. [1 ]
机构：
[1] Russian Acad Sci, Inst Phys Chem & Electrochem, Moscow 119991, Russia
来源：
RADIATION PHYSICS AND CHEMISTRY | 2008年 / 77卷 / 08期
关键词：
water; aqueous solutions; oxygen; hydrogen; hydrogen peroxide; radiolysis; reaction; rate constant; kinetic; simulating;
D O I：
10.1016/j.radphyschem.2007.12.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetic model for the radiolysis of pure water describing the formation of H-2, H2O2 and O-2 and the radiation chemical transformations of aqueous solutions containing these compounds over a broad range of concentrations, pH, absorbed doses and dose rates is proposed and substantiated. The model includes a set of chemical reactions with optimized rate constants and the radiation chemical yields of radiolysis products. The model applicability to the description of the whole set of data on the radiation chemical transformations of water and aqueous solutions of H-2, H2O2 and O-2 is demonstrated. (C) 2007 Published by Elsevier Ltd.
引用
收藏
页码：928 / 935
页数：8
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