PALLADIUM-CATALYZED MIZOROKI-HECK TYPE REACTION WITH ARYLIODINE DIACETATES USING HYDRAZONE LIGAND

被引：9

作者：

Mino, Takashi ^{[1
]}

Watanabe, Kohei ^{[1
]}

Abe, Taichi ^{[1
]}

Kogure, Taketo ^{[1
]}

Sakamoto, Masami ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 2638522, Japan

来源：

HETEROCYCLES | 2013年 / 87卷 / 10期

关键词：

Palladium Catalyst; Mizoroki-Heck Type Reaction; Heterocyclic Hydrazone; Hypervalent Iodine Reagent; HYPERVALENT IODINE REAGENTS; COUPLING REACTIONS; ROOM-TEMPERATURE; PD-COMPLEX; ALKENES; CHLORIDES; ACIDS;

D O I：

10.3987/COM-13-12786

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We developed a palladium-catalyzed Mizoroki-Heck type reaction of olefins with such hypervalent iodine reagents as iodobenzene diacetate in good to high yields using 2 mol% of a heterocyclic hydrazone (1b)-Pd(OAc)(2) system in NMP under air at 90 degrees C.

引用

页码：2015 / 2021

页数：7

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