Synthesis, structures, and luminescent properties of aluminum complexes with chelating anilido-imine ligands

被引：27

作者：

Liu, XM ^{[1
]}

Xia, H ^{[1
]}

Gao, W ^{[1
]}

Ye, L ^{[1
]}

Mu, Y ^{[1
]}

Su, Q ^{[1
]}

Ren, Y ^{[1
]}

机构：

[1] Jilin Univ, Sch Chem, Key Lab Supramol Struct & Mat, Minist Educ, Changchun 130012, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 06期

关键词：

aluminum; N ligands; luminescence;

D O I：

10.1002/ejic.200500740

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of a number of four-coordinate aluminum complexes, ortho-C6H4(NAr')(CH=NAr")AlCl2 [Ar' = Ar" = 2,6-iPr(2)C(6)H(3) (2a); Ar' = 2,6-iPr(2)C(6)H(3), Ar" = 2,6-Me2C6H3 (2b); Ar' = Ar" = 2,6-Me2C6H3 (2c); Ar' = p-MeC6H4, Ar" = 2,6-iPr(2)C(6)H(3) (2d)], are described. Complexes 2a-2d were synthesized from the reaction of AlCl3 with lithium salt of the corresponding ligand at room temperature. All complexes were characterized by H-1 and C-13 NMR spectroscopy and molecular structures of complexes 2a, 2b, and 2d were determined by X-ray crystallography. Luminescent properties of complexes 2a-2d in both solution and the solid state were studied. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

引用

页码：1216 / 1222

页数：7

共 73 条

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