Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles

被引：7

作者：

Bortoluzzi, Marco ^{[1
]}

Scrivanti, Alberto ^{[1
]}

Reolon, Andrea ^{[1
]}

Amadio, Emanuele ^{[1
]}

Bertolasi, Valerio ^{[2
,3
]}

机构：

[1] Dipartimento Sci Mol & Nanosistemi, I-30123 Venice, Italy

[2] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

[3] Univ Ferrara, Ctr Strutturist Diffrattomet, I-44100 Ferrara, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 33卷

关键词：

Gold(III); Chloro-complexes; N-donor ligands; Pyridine; Triazole; ANTIPROLIFERATIVE PROPERTIES; 1,3-DIPOLAR CYCLOADDITIONS; ANTICANCER AGENTS; SOLUTION BEHAVIOR; TERMINAL ALKYNES; GOLD; CATALYSIS; CHEMISTRY; AZIDES;

D O I：

10.1016/j.inoche.2013.04.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry towards the Au(III) metal centre of the pyridine-triazole ligands 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Ph)) and 2-[(4-pentyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Pent))has been explored and complexes having formulae AuCl3(pytz(Ph)) (1(Ph)) and AuCl3(pytz(Pent)) (1(Pent)) have been isolated and characterised. Reaction of 1(Ph) with AgClO4 allowed the preparation of the compound [AuCl2(pytz(Ph))](ClO4) (2(Ph)). Reaction of 1(Ph) and 1(Pent) with K[AuCl4]center dot 2H(2)O led to the formation of the salts [Hpytz(Ph)][AuCl4] (3(Ph)) and [Hpytz(Pent)][AuCl4] (3(Pent)). (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：82 / 85

页数：4

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