Influence of dehydration on the electron spin resonance in the Cu3[W(CN)8]2(Pyrimidine)2 • 8H2O molecular magnet

被引:2
|
作者
Koplak, O. V. [1 ]
Kirman, M. V. [1 ]
Dmitriev, A. I. [1 ]
Tokoro, H. [2 ]
Ohkoshi, S. [2 ]
Morgunov, R. B. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[2] Univ Tokyo, Bunkyo Ku, Tokyo, Japan
基金
俄罗斯基础研究基金会;
关键词
TEMPERATURE; MAGNETIZATION; FERRIMAGNET;
D O I
10.1134/S1063783413050168
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The influence of dehydration on the electron spin resonance spectra in the Cu-3[W(CN)(8)](2)(pyrimidine)(2) center dot 8H(2)O molecular magnet has been found. It has been established that two ferromagnetic phases with the Curie temperatures of similar to 12-17 and similar to 50 K, which correspond to two different lines of the ferromagnetic resonance, are present in crystals. Dehydration leads to increasing the Curie temperature of the low-temperature phase from 12 to 17 K and to varying the temperature dependences of the spectrum parameters of the high-temperature phase (the resonant field and the width line).
引用
收藏
页码:990 / 994
页数:5
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