Conversion of carbonimidodithioates to carbamates

被引：7

作者：

Anbazhagan, M ^{[1
]}

Reddy, TI ^{[1
]}

Rajappa, S ^{[1
]}

机构：

[1] NATL CHEM LAB,DIV ORGAN CHEM SYNTH,PUNE 411008,MAHARASHTRA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 11期

关键词：

D O I：

10.1039/a700166e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbonimidodithioates derived from primary amines or alpha-amino acid esters have been converted to N-benzyloxycarbonyl derivatives under mild conditions by treatment first with sodium benzyl alcoholate and then with water, N-Benzyloxycarbonyl alpha-amino acids have been generated from the methyl esters by alkaline hydrolysis or from the allyl esters by Pd-0-catalysed de-allylation.

引用

页码：1623 / 1627

页数：5

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