Transition-Metal-Free Aerobic Oxidative Cleavage of C-C Bonds in a-Hydroxy Ketones and Mechanistic Insight to the Reaction Pathway

被引：128
|
作者：
Liu, Hui [1 ]
Dong, Chao [1 ]
Zhang, Zeguang [1 ]
Wu, Peiyu [1 ]
Jiang, Xuefeng [1 ]
机构：
[1] E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Dept Chem, Shanghai 200062, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 50期
关键词：
C?C bond cleavage; esterification; a-hydroxy ketones; oxidation; synthetic methods; MOLECULAR-OXYGEN; DIOXYGEN ACTIVATION; PHOTOOXYGENATION; DIOXINDOLE;
D O I：
10.1002/anie.201207206
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：12570 / 12574
页数：5
相关论文
共 50 条
  • [1] Mechanistic Insight to the Reaction Pathway of Aerobic Oxidative C-C Bond Cleavage of α-Hydroxy Ketones
    Liu, Hui
    Jiang, Xuefeng
    SYNLETT, 2013, 24 (11) : 1311 - 1315
  • [2] Transition-Metal-Free and Selective Deconstructive Carbonyl Olefination of a-Hydroxy Ketones: A Complementary Approach to Knoevenagel Reaction
    Sandeep
    Saini, Vaneet
    Chayawan
    Chaudhary, Ganga R.
    Venugopalan, Paloth
    Kumar, Anil
    SYNTHESIS-STUTTGART, 2023, 55 (19): : 3186 - 3194
  • [3] Metal-free Photocatalytic Aerobic Oxidative Cleavage of C-C Bonds in 1,2-Diols
    Zhu, Rui
    Zhou, Gongyu
    Teng, Jia-nan
    Li, Xinglong
    Fu, Yao
    CHEMSUSCHEM, 2020, 13 (19) : 5248 - 5255
  • [4] Copper-Catalyzed Aerobic Oxidative Cleavage of C-C Bonds in Epoxides Leading to Aryl Ketones
    Gu, Lijun
    Jin, Cheng
    Zhang, Hongtao
    Zhang, Lizhu
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (17): : 8453 - 8456
  • [5] Metal-free oxidative cleavage of the C-C bond in α-hydroxy-β-oxophosphonates
    Battula, Satyanarayana
    Kumar, Atul
    Ahmed, Qazi Naveed
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (39) : 9953 - 9956
  • [6] Transition-metal-free multinitrogenation of amides by C-C bond cleavage: a new approach to tetrazoles
    Li, Lian-Hua
    Niu, Zhi-Jie
    Li, Ying-Xiu
    Liang, Yong-Min
    CHEMICAL COMMUNICATIONS, 2018, 54 (79) : 11148 - 11151
  • [7] Transition-metal-free Oxidative Coupling Reactions for the Formation of C-C and C-N Bonds Mediated by TEMPO and its Derivatives
    Murarka, Sandip
    Wertz, Sebastian
    Studer, Armido
    CHIMIA, 2012, 66 (06) : 413 - 417
  • [8] Aerobic photo-oxidative cleavage of the C-C double bonds of styrenes
    Hirashima, Shin-ichi
    Kudo, Yasuhisa
    Nobuta, Tomoya
    Tada, Norihiro
    Itoh, Akichika
    TETRAHEDRON LETTERS, 2009, 50 (30) : 4328 - 4330
  • [9] Transition metal-free aerobic oxidative cleavage of the C-N bonds of α-amino esters
    Tan, Shenpeng
    Li, Feng
    Park, Soojun
    Kim, Sanghee
    ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (23) : 3854 - 3858
  • [10] Oxidative cleavage of the C-H, C-C, C-O bonds by transition metal atoms
    Wang, Jiaqi
    Wilson, Angela K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
12345