Desorption of hydrogen from an electrode surface under influence of an external magnetic field - In-situ microscopic observations

被引：59

作者：

Koza, Jakub Adam ^{[1
]}

Muehlenhoff, Sascha ^{[2
]}

Uhlemann, Margitta ^{[1
]}

Eckert, Kerstin ^{[2
]}

Gebert, Annett ^{[1
]}

Schultz, Ludwig ^{[1
]}

机构：

[1] Leibniz Inst Solid State & Mat Res IFW Dresden, Inst Metall Mat, D-01171 Dresden, Germany

[2] Tech Univ Dresden, Inst Fluid Mech, D-01069 Dresden, Germany

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2009年 / 11卷 / 02期

关键词：

Magnetoelectrodeposition; Lorentz force; Micro-MHD; Shadowgraph technique; Desorption of hydrogen; CONVECTION;

D O I：

10.1016/j.elecom.2008.12.010

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of a magnetic field in the perpendicular-to-electrode configuration on the hydrogen evolution reaction (HER) was investigated during the deposition of Co. An enhanced desorption of hydrogen in the form of numerous small bubbles was found by combining potentiostatic investigations, coupled with an electrochemical quartz crystal microbalance (EQCM), and simultaneous microscopic observations of the electrode surface. The results are consistent with the recently proposed qualitative model [J.A. Koza, M. Uhlemann, A. Gebert, L Schultz, Electrochem. Commun. 10 (2008) 1330]. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：425 / 429

页数：5

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