High-temperature X-ray analysis of phase evolution in lithium ion conductor Li1.5Al0.5Ge1.5(PO4)3

被引：26
作者：
He Kun [1 ]
Wang Yanhang [1 ]
Zu Chengkui [1 ]
Liu Yonghua [1 ]
Zhao Huifeng [1 ]
Chen Jiang [1 ]
Han Bin [1 ]
Ma Juanrong [1 ]
机构：
[1] China Bldg Mat Acad, Inst Quartz & Special Glasses, Beijing 100024, Peoples R China
来源：
MATERIALS CHARACTERIZATION | 2013年 / 80卷
关键词：
High temperature X-ray diffraction; Glass-ceramics; Ionic conductivity; Rietveld refinement; GLASS-CERAMICS; CRYSTALLIZATION; NASICON; TI;
D O I：
10.1016/j.matchar.2013.03.012
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Series of Li1.5Al0.5Ge1.5(PO4)(3) glass ceramic samples were prepared in this work through the change of heat treatment temperature from 650 to 1050 degrees C. The structures of glass ceramic samples were characterized by means of high temperature X-ray diffraction and Field Emission Scanning Electron Microscope. And the lithium ionic conductivity was analyzed through AC impedance spectroscopy. Through heat treatment at 850 degrees C for 4 h for the base glass sample, we obtained a maximum conductivity of 5.8 x 10(-4) S/cm at room temperature. Crown Copyright (C) 2013 Published by Elsevier Inc. All rights reserved.
引用
收藏
页码：86 / 91
页数：6
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