Synthesis and Structure of a HgCl2 Coordination Polymer With 1,4-Bis(benzimidazole-1-yl-methylene)benzene (bbmb)

被引：1

作者：

Chen, Yuqing ^{[1
]}

Chen, Chunguang ^{[1
]}

Chen, Hong ^{[1
]}

Cao, Ting ^{[1
]}

Yue, Zhongcheng ^{[1
]}

Liu, Xiucun ^{[1
]}

Niu, Yunyin ^{[1
,2
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450052, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210008, Jiangsu, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 09期

关键词：

Coordination polymer; crystal structure; mercury dichloride; BRIDGED COPPER(II) COMPLEXES; CRYSTAL-STRUCTURES; LIGANDS;

D O I：

10.1080/15533174.2012.758152

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this study, solution reaction of mercury dichloride with organic multifunctional ligand 1,4-bis(benzimidazole-1-yl-methylene)benzene generated a 1D polymer [HgCl2 (bbmb)center dot 2H(2)O center dot CH3OH](n) 1, and the crystal structure has been determined (C46H60Cl4Hg2N8O10), Mr = 1428.00, a = 14.703(15) angstrom, b = 17.248(17) angstrom, c = 14.91(2) angstrom, beta= 114.869(10)degrees, space group C-2/c, Z = 2, and V = 3430(7) angstrom(3). In 1 the tetrahedral coordination of Hg(II) and the conformation of the bbmb ligand make it a wave-shaped structure.

引用

页码：1307 / 1310

页数：4

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