Regioselective Synthesis of α-Phosphinoylnaphthols through Rhodium-Catalyzed Annulation of 1-Alkynylphosphine Oxides with Sulfoxonium Ylides

被引：8

作者：

Xie, Wucheng ^{[1
]}

Lin, Binting ^{[1
]}

Jian, Xinyi ^{[1
]}

Lin, Qinhong ^{[1
]}

Shi, Junjun ^{[1
]}

机构：

[1] Foshan Univ, Sch Environm & Chem Engn, Foshan City Engn & Technol Res Ctr Bioact Nat Pro, 18 Jiang Wan Yi Lu, Foshan, Guangdong, Peoples R China

来源：

SYNLETT | 2020年 / 31卷 / 15期

关键词：

C-H activation; rhodium catalysis; cyclization; carbocycles; phosphinoylnaphthols; ylides; RH(III)-CATALYZED C-H; N BOND FORMATION; ACTIVATION; FUNCTIONALIZATION; ARYL; ISOCOUMARINS; DERIVATIVES; INHIBITORS; NAPHTHOLS; LIGANDS;

D O I：

10.1055/s-0040-1707892

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Phosphinoylnaphthols were obtained by redox-neutral annulation of 1-alkynylphosphine oxides with alpha-carbonyl sulfoxonium ylides under rhodium(III) catalysis. This protocol shows good regioselectivity and broad functional-group tolerance.

引用

页码：1482 / 1486

页数：5

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