Regioselective Synthesis of α-Phosphinoylnaphthols through Rhodium-Catalyzed Annulation of 1-Alkynylphosphine Oxides with Sulfoxonium Ylides

被引：8
作者：
Xie, Wucheng [1 ]
Lin, Binting [1 ]
Jian, Xinyi [1 ]
Lin, Qinhong [1 ]
Shi, Junjun [1 ]
机构：
[1] Foshan Univ, Sch Environm & Chem Engn, Foshan City Engn & Technol Res Ctr Bioact Nat Pro, 18 Jiang Wan Yi Lu, Foshan, Guangdong, Peoples R China
来源：
SYNLETT | 2020年 / 31卷 / 15期
关键词：
C-H activation; rhodium catalysis; cyclization; carbocycles; phosphinoylnaphthols; ylides; RH(III)-CATALYZED C-H; N BOND FORMATION; ACTIVATION; FUNCTIONALIZATION; ARYL; ISOCOUMARINS; DERIVATIVES; INHIBITORS; NAPHTHOLS; LIGANDS;
D O I：
10.1055/s-0040-1707892
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha-Phosphinoylnaphthols were obtained by redox-neutral annulation of 1-alkynylphosphine oxides with alpha-carbonyl sulfoxonium ylides under rhodium(III) catalysis. This protocol shows good regioselectivity and broad functional-group tolerance.
引用
收藏
页码：1482 / 1486
页数：5
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