An Uncommon Carboxyl-Decorated Metal-Organic Framework with Selective Gas Adsorption and Catalytic Conversion of CO2

A new three-dimensional (3D) framework, [Ni(btzip)(H(2)btzip)]center dot 2DMF center dot 2H(2)O (1) (H(2)btzip= 4,6-bis(triazol-1-yl)isophthalic acid) as an acidic heterogeneous catalyst was constructed by the reaction of nickel wire and a triazolyl-carboxyl linker. Framework 1 possesses intersected 2D channels decorated by free COOH groups and uncoordinated triazolyl N atoms, leading to not only high CO2 and C2H6 adsorption capacity but also significant selective capture for CO2 and C2H6 over CH4 and CO in 273-333 K. Moreover, 1 reveals chemical stability toward water. Grand Canonical Monte Carlo simulations confirmed the multiple CO2-and C2H6-philic sites. As a result of the presence of accessible Bronsted acidic COOH groups in the channels, the activated framework demonstrates highly efficient catalytic activity in the cycloaddition reaction of CO2 with propylene oxide/4-chloro-methyl-1,3-dioxolan-2-one/3-butoxy-1,2-epoxypropane into cyclic carbonates.