The catalytic activity of a novel recyclable alkoxypalladium complex in Suzuki reaction

被引：12
作者：
Li, Yabo [1 ]
Mi, Xia [1 ]
Huang, Mengmeng [1 ]
Cai, Ranran [1 ]
Wu, Yangjie [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Zhengzhou 450052, Peoples R China
来源：
TETRAHEDRON | 2012年 / 68卷 / 40期
基金：
中国国家自然科学基金;
关键词：
Alkoxypalladium complex; Recyclable catalyst; Suzuki cross-coupling reaction; Aryl halides; Boronic acid; CROSS-COUPLING REACTIONS; ORTHO-SUBSTITUTED BIARYLS; ARYL CHLORIDES; PALLADIUM CATALYSTS; DIHYDROFOLATE-REDUCTASE; MIYAURA COUPLINGS; ROOM-TEMPERATURE; HECK REACTION; LIGANDS; NANOPARTICLES;
D O I：
10.1016/j.tet.2012.07.026
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel palladium complex based on N,O-ligand was synthesized, which shows a high catalytic activity in the Suzuki cross-coupling reaction without using any phosphine ligand. More importantly, no significant loss of the catalytic activity was observed after six recycles. We suggest that this catalyst has commercial and industrial potential in the future. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8502 / 8508
页数：7
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