Hybrid Fly Ash-Based Geopolymeric Foams: Microstructural, Thermal and Mechanical Properties

被引:19
|
作者
Roviello, Giuseppina [1 ,2 ]
Ricciotti, Laura [1 ]
Molino, Antonio Jacopo [1 ]
Menna, Costantino [3 ]
Ferone, Claudio [1 ,2 ]
Asprone, Domenico [3 ]
Cioffi, Raffaele [1 ,2 ]
Ferrandiz-Mas, Veronica [4 ]
Russo, Pietro [5 ]
Tarallo, Oreste [6 ]
机构
[1] Univ Naples Parthenope, Ctr Direz, Dept Engn, Isola C4, I-80143 Naples, Italy
[2] Natl Consortium Sci & Technol Mat, INSTM Res Grp Napoli Parthenope, Via G Giusti 9, I-50121 Florence, Italy
[3] Univ Naples Federico II, Dept Struct Engn & Architecture, Via Claudio 21, I-80125 Naples, Italy
[4] Univ Bath, Dept Architecture & Civil Engn, BRE Ctr Innovat Construct Mat BRE CICM, Bath 04530, Avon, England
[5] CNR, Inst Polymers Composites & Biomat, Via Campi Flegrei 34, I-80078 Pozzuoli, NA, Italy
[6] Univ Napoli Federico II, Dept Chem Sci, Complesso Univ Monte S Angelo,Via Cintia, I-80126 Naples, Italy
关键词
hybrid foams; lightweight material; geopolymer; fly ash; polysiloxanes; microtomography; thermal conductivity; mechanical properties; SUSTAINABLE CONSTRUCTION; WASTE MANAGEMENT; PORTLAND-CEMENT;
D O I
10.3390/ma13132919
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This research investigates the preparation and characterization of new organic-inorganic geopolymeric foams obtained by simultaneously reacting coal fly ash and an alkali silicate solution with polysiloxane oligomers. Foaming was realized in situ using Si(0)as a blowing agent. Samples with density ranging from 0.3 to 0.7 g/cm(3)that show good mechanical properties (with compressive strength up to approximate to 5 MPa for a density of 0.7 g/cm(3)) along with thermal performances (lambda = 0.145 +/- 0.001 W/m center dot K for the foamed sample with density 0.330 g/cm(3)) comparable to commercial lightweight materials used in the field of thermal insulation were prepared. Since these foams were obtained by valorizing waste byproducts, they could be considered as low environmental impact materials and, hence, with promising perspectives towards the circular economy.
引用
收藏
页码:1 / 19
页数:19
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