Periodic electron circulation induced by circularly polarized laser pulses: Quantum model simulations for Mg porphyrin

被引：155

作者：

Barth, Ingo ^{[1
]}

Manz, Jorn ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期

关键词：

electronic structure; laser chemistry; porphyrinoids; quantum dynamics;

D O I：

10.1002/anie.200504147

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

What goes round comes round! Quantum dynamical simulations predict that ultra-short circularly polarized laser pulses can selectively induce the circulation of electrons in a ring-shaped molecule - with near equal laser and electron periods below one femtosecond (see figure). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2962 / 2965

页数：4

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