Construction of Two Different Topological Frameworks of Mn(II) Coordination Polymers Based on the Dicarboxylate and Imidazole-Containing Ligands

被引：0

作者：

Wang, Aidong ^{[1
,2
]}

Hu, Fengkai ^{[1
]}

Ke, Zhongcheng ^{[1
]}

Fang, Chen ^{[3
]}

Wei, Wei ^{[1
]}

机构：

[1] Coll Huangshan, Dept Chem, Huangshan 245041, Peoples R China

[2] Ocean Univ China, Coll Chem & Chem Engn, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao, Shandong, Peoples R China

[3] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 10期

关键词：

crystal structure; Mn(II); topology; 1D;

D O I：

10.1080/15533174.2013.763276

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Mn(II) coordination polymers, {[Mn(5-CH3-ip)(bib)]2H(2)O}(n) (1) and [Mn (5-CH3- ip)(bib)(0.5)](n) (2) (5-CH3-ip = 5-Methyl-1,3-benzenedicarboxylic acid bib = 1,4-bis(imidazol-1-yl) benzene), have been synthesized and characterized by elemental analysis, IR, and X-ray diffraction. Complex 1 shows a 2D layer structure. Complex 2 is a 3D structure (3,7)-connected topology with a Schafli symbol of (6(20).8).(6(3)). The topology has been well controlled by pH value.

引用

页码：1571 / 1575

页数：5

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