Preparation of CTAB-Assisted Hexagonal Platelet Co(OH)2/Graphene Hybrid Composite as Efficient Supercapacitor Electrode Material

被引:124
作者
Ghosh, Debasis [1 ]
Giri, Soumen [1 ]
Das, Chapal Kumar [1 ]
机构
[1] Indian Inst Technol, Ctr Mat Sci, Kharagpur 721302, W Bengal, India
关键词
Cobalt hydroxide; Graphene; Specific capacitance; Supercapacitor; ELECTROCHEMICAL CAPACITANCE; COBALT HYDROXIDE; MICROSPHERES; PERFORMANCE; ARRAYS;
D O I
10.1021/sc400055z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, our work deals with the preparation of cetyl trimethylammonium bromide (CTAB)assisted hexagonal platelet beta Co(OH)(2) via a simple hydrothermal process and its graphene-based hybrid composite with improved electrochemical properties. The prepared materials were successfully characterized by FTIR, XRD, FESEM, TEM, and TGA analysis. The materials were subjected to electrochemical analysis by a three electrode system in a 6 M KOH electrolyte in terms of a cyclic voltammetry, cyclic charge-discharge, and electrochemical impedance study. The CTAB-assisted Co(OH)(2) with hexagonal architecture exhibited the highest specific capacitance of 312 F/g at a 2 mV/s scan rate and 285 F/g at a 2 A/g constant discharge current density. The high utility of pseudocapacitive Co(OH)(2) is achieved only in its graphene-based hybrid composite, which responded with specific capacitance of 532 F/g at a 2A/g current density and a 94% specific capacitance retention over 500 charge discharge cycles.
引用
收藏
页码:1135 / 1142
页数:8
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