From click to ceramic: An efficient way to generate multielement Si/Zr/C clicked-polymer-derived ceramics (cPDC)

被引：14

作者：

Bouzat, Fabien ^{[1
]}

Foucaud, Sylvie ^{[1
]}

Leconte, Yann ^{[2
]}

Maitre, Alexandre ^{[1
]}

Lucas, Romain ^{[1
]}

机构：

[1] SPCTS CNRS, Ctr Europeen Ceram, UMR 7315, F-87068 Limoges, France

[2] CEA, CEA CNRS, IRAMIS, SPAM,LFP, F-91191 Gif Sur Yvette, France

来源：

MATERIALS LETTERS | 2013年 / 106卷

关键词：

Ceramics; Composites; Pyrolysis; ZrC; SiC; Click chemistry; POLYCARBOSILANE; CHALLENGES; AZIDE;

D O I：

10.1016/j.matlet.2013.05.064

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Clicked-polymer-derived ceramics (cPDC) were elaborated using no chromatographic purification steps. Starting from suitable monomers, three original silicon-contained clicked-polymers P1-3 were synthesized in good yields, using the copper-catalyzed azide-alkyne cycloaddition (CuAAC). Then, the thermal behaviors of the organic materials were investigated until 1400 degrees C. Thanks to XRD analysis, an alpha-SiC was unusually observed for materials obtained from P1 and P2. Thereby, pyrolysis of polymer P3 led to a composite alpha-SiC-ZrC. The free carbon, initially observed after pyrolytic treatment of P1 and P2, was removed in the final material C3. A structure for P3 was then proposed on the evidence of IR and NMR spectroscopic data. Hence, the polymer-derived ceramics route was synergistically associated to the CuAAC to generate high performance materials. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：337 / 340

页数：4

共 31 条

[11] Effect of the polycarbosilane structure on its final ceramic yield [J].

Li, Houbu ;

Zhang, Litong ;

Cheng, Laifei ;

Wang, Yiguang ;

Yu, Zhaoju ;

Huang, Muhe ;

Tu, Huibin ;

Xia, Haiping .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2008, 28 (04) :887-891

[12] Combination of SHS and SPS Techniques for fabrication of fully dense ZrB2-ZrC-SiC composites [J].

Licheri, Roberta ;

Orru, Roberto ;

Musa, Clara ;

Cao, Giacomo .

MATERIALS LETTERS, 2008, 62 (03) :432-435

[13]

Liu LH, 2003, CHINESE J POLYM SCI, V21, P99

[14] Crystallisation behaviour and polytype transformation of polymer-derived silicon carbide [J].

Martin, HP ;

Muller, E ;

Irmer, G ;

Babonneau, F .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1997, 17 (05) :659-666

[15] Design, preparation and properties of non-oxide CMCs for application in engines and nuclear reactors: an overview [J].

Naslain, R .

COMPOSITES SCIENCE AND TECHNOLOGY, 2004, 64 (02) :155-170

[16] Stereoselective ring-opening polymerization of a racemic lactide by using achiral salen- and homosalen-aluminum complexes [J].

Nomura, Nobuyoshi ;

Ishii, Ryohei ;

Yamamoto, Yoshihiko ;

Kondo, Tadao .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (16) :4433-4451

[17] Structural Analysis of Porphyrin Multilayer Films on ITO Assembled Using Copper(I)-Catalyzed Azide-Alkyne Cycloaddition by ATR IR [J].

Palomaki, Peter K. B. ;

Dinolfo, Peter H. .

ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (12) :4703-4713

[18] From trimethylvinylsilane to ZrC-SiC hybrid materials [J].

Pizon, David ;

Lucas, Romain ;

Chehaidi, Sirine ;

Foucaud, Sylvie ;

Maitre, Alexandre .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2011, 31 (14) :2687-2690

[19] Synthesis of crystalline SiC nanofiber through the pyrolysis of polycarbomethylsilane coated platelet carbon nanofiber [J].

Qiao, W. M. ;

Lim, S. Y. ;

Yoon, S. H. ;

Mochida, I. ;

Ling, L. C. ;

Yang, J. H. .

APPLIED SURFACE SCIENCE, 2007, 253 (10) :4467-4471

[20] Click polymerization [J].

Qin, Anjun ;

Lam, Jacky W. Y. ;

Tang, Ben Zhong .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (07) :2522-2544

← 1 2 3 4 →