Well Known or New? Synthesis and Structure Assignment of Binary C2N14 Compounds Reinvestigated

被引：23

作者：

Banert, Klaus ^{[1
]}

Richter, Sebastian ^{[1
]}

Schaarschmidt, Dieter ^{[1
]}

Lang, Heinrich ^{[1
]}

机构：

[1] Tech Univ Chemnitz, D-09111 Chemnitz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 12期

关键词：

azides; cyclization; nitrogen-rich compounds; NMR spectroscopy; reactive intermediates; TETRAZOLE;

D O I：

10.1002/anie.201209170

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rapid ring closure transforms the tetraazide 1, which was thought to have been characterized at room temperature in 1961 and 2009, into the tetrazole 2. Consequently, the previously synthesized compounds actually are identical with heterocycle 2, which was also prepared by a third method in 2011. After its generation at low temperature, the open-chain compound 1 and its cyclization reaction have now been analyzed for the first time. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3499 / 3502

页数：4

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