Structural control in enzymatic oxidative polymerization of phenols with varying the solvent and substituent nature

被引：30
作者：
Mita, N
Tawaki, S
Uyama, H
Kobayashi, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan
[2] Japan Chem Innovat Inst, NIMC, Joint Res Ctr Precis Polymerizat, Tsukuba, Ibaraki 3058565, Japan
[3] Mitsui Chem Inc, Chem Synth Lab, Sodegaura, Chiba 2990265, Japan
来源：
CHEMISTRY LETTERS | 2002年 / 03期
关键词：
D O I：
10.1246/cl.2002.402
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Control of the coupling selectivity (regioseleetivity) in the horseradish peroxidase-catalyzed oxidative polymerization of 4-substituted phenols has been achieved by changing the hydrophobic parameters of the monomer substituent and organic solvent (pi and log P, respectively), yielding soluble polyphenols with a different ratio of phenylene/oxyphenylene units.
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页码：402 / 403
页数：2
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