Structural control in enzymatic oxidative polymerization of phenols with varying the solvent and substituent nature

被引：30

作者：

Mita, N

Tawaki, S

Uyama, H

Kobayashi, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

[2] Japan Chem Innovat Inst, NIMC, Joint Res Ctr Precis Polymerizat, Tsukuba, Ibaraki 3058565, Japan

[3] Mitsui Chem Inc, Chem Synth Lab, Sodegaura, Chiba 2990265, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 03期

关键词：

D O I：

10.1246/cl.2002.402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Control of the coupling selectivity (regioseleetivity) in the horseradish peroxidase-catalyzed oxidative polymerization of 4-substituted phenols has been achieved by changing the hydrophobic parameters of the monomer substituent and organic solvent (pi and log P, respectively), yielding soluble polyphenols with a different ratio of phenylene/oxyphenylene units.

引用

页码：402 / 403

页数：2

共 5 条

[1] Molecular weight control in enzymatic polymerization of phenols in nonaqueous media
Ayyagari, M
Akkara, JA
Kaplan, DL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 4 - PMSE
[2] Radical-controlled oxidative polymerization of phenols. Substituent effect of phenol monomers on the reaction rate
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Fujisawa, K
Moro-oka, Y
Namekawa, S
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POLYMERS FOR ADVANCED TECHNOLOGIES, 2000, 11 (8-12) : 733 - 738
[3] Synthesis, Structural Characterization, Enzymatic and Oxidative Polymerization of 2,6-Diaminopyridine
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JOURNAL OF FLUORESCENCE, 2020, 30 (01) : 157 - 174
[4] Synthesis, Structural Characterization, Enzymatic and Oxidative Polymerization of 2,6-Diaminopyridine
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Journal of Fluorescence, 2020, 30 : 157 - 174
[5] Control of structure ano molecular weight of polyphenols in enzymatic-oxidative polymerization.
Mita, N
Oguchi, T
Tawaki, S
Uyama, H
Kobayashi, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U376 - U377

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