High thermoelectric performance in tellurium free p-type AgSbSe2

被引:221
作者
Guin, Satya N. [1 ]
Chatterjee, Arindom [1 ]
Negi, Devendra Singh [2 ,3 ]
Datta, Ranjan [2 ,3 ]
Biswas, Kanishka [1 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, New Chem Unit, Bangalore 560064, Karnataka, India
[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[3] Jawaharlal Nehru Ctr Adv Sci Res, Int Ctr Mat Sci, Bangalore 560064, Karnataka, India
关键词
FIGURE-OF-MERIT; ENHANCED FIGURE; PBSE; NANOSTRUCTURES; ELEMENTS; AGSBTE2; SYSTEMS; PBTE; CA;
D O I
10.1039/c3ee41935e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Enhanced electrical transport and ultra low thermal conductivity resulted in a high thermoelectric figure of merit, ZT, of similar to 1 and similar to 1.15 at similar to 680 K in 4 mol% Pb and 2 mol% Bi doped AgSbSe2, which are 150 and 190% higher compared to that of the pristine sample, respectively. With this excellent thermoelectric performance, p-type AgSbSe2, constituting earth abundant Se, offers promise to replace traditional metal tellurides containing expensive and scarce Te for mid temperature (350-700 K) thermoelectric applications.
引用
收藏
页码:2603 / 2608
页数:6
相关论文
共 40 条
  • [11] Cubic AgPbmSbTe2+m:: Bulk thermoelectric materials with high figure of merit
    Hsu, KF
    Loo, S
    Guo, F
    Chen, W
    Dyck, JS
    Uher, C
    Hogan, T
    Polychroniadis, EK
    Kanatzidis, MG
    [J]. SCIENCE, 2004, 303 (5659) : 818 - 821
  • [12] Upper crustal abundances of trace elements: A revision and update
    Hu, Zhaochu
    Gao, Shan
    [J]. CHEMICAL GEOLOGY, 2008, 253 (3-4) : 205 - 221
  • [13] Doping Effects on the Thermoelectric Properties of AgSbTe2
    Jovovic, V.
    Heremans, J. P.
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2009, 38 (07) : 1504 - 1509
  • [14] Measurements of the energy band gap and valence band structure of AgSbTe2
    Jovovic, V.
    Heremans, J. P.
    [J]. PHYSICAL REVIEW B, 2008, 77 (24):
  • [15] High-Performance Tellurium-Free Thermoelectrics: All-Scale Hierarchical Structuring of p-Type PbSe-MSe Systems (M = Ca, Sr, Ba)
    Lee, Yeseul
    Lo, Shih-Han
    Androulakis, John
    Wu, Chun-I
    Zhao, Li-Dong
    Chung, Duck-Young
    Hogan, Timothy P.
    Dravid, Vinayak P.
    Kanatzidis, Mercouri G.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (13) : 5152 - 5160
  • [16] High-performance nanostructured thermoelectric materials
    Li, Jing-Feng
    Liu, Wei-Shu
    Zhao, Li-Dong
    Zhou, Min
    [J]. NPG ASIA MATERIALS, 2010, 2 (04) : 152 - 158
  • [17] Liu HL, 2012, NAT MATER, V11, P422, DOI [10.1038/NMAT3273, 10.1038/nmat3273]
  • [18] Revisiting some chalcogenides for thermoelectricity
    Maignan, Antoine
    Guilmeau, Emmanuel
    Gascoin, Franck
    Breard, Yohann
    Hardy, Vincent
    [J]. SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2012, 13 (05)
  • [19] Mehta RJ, 2012, NAT MATER, V11, P233, DOI [10.1038/NMAT3213, 10.1038/nmat3213]
  • [20] Intrinsically minimal thermal conductivity in cubic I-V-VI2 semiconductors
    Morelli, D. T.
    Jovovic, V.
    Heremans, J. P.
    [J]. PHYSICAL REVIEW LETTERS, 2008, 101 (03)