Protein film cryovoltammetry: demonstrations with a 7Fe ([3Fe-4S]+[4Fe-4S]) ferredoxin

被引：11

作者：

McEvoy, JP ^{[1
]}

Armstrong, FA ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a903222c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low-temperature protein film voltammetry, demonstrated here by studies of Fe-S clusters in the 7Fe ferredoxin from Thermoplasma acidophilum, offers a novel way to investigate active site redox reactions, allowing resolution of complex transformations and transient states, and providing an immediate and sensitive gauge of solvent effects.

引用

页码：1635 / 1636

页数：2

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