Frozen-State Polymerization as a Tool in Conductivity Enhancement of Polypyrrole

被引:12
作者
Minisy, Islam M. [1 ,2 ]
Bober, Patrycja [1 ]
机构
[1] Acad Sci Czech Republ, Inst Macromol Chem, Prague 16206 6, Czech Republic
[2] Charles Univ Prague, Fac Sci, Prague 12843 2, Czech Republic
关键词
conducting polymers; frozen polymerization; organic dyes; polypyrrole; ONE-DIMENSIONAL POLYPYRROLE; MORPHOLOGY; NANOTUBES; SURFACTANTS; REDUCTION; DYES;
D O I
10.1002/marc.202000364
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polypyrrole (PPy) is oxidatively polymerized in the frozen state at -24 degrees C in the presence of various organic dyes as morphology guiding agents in order to form homogeneous 1D PPy nanoforms. The freezing polymerization of pyrrole has a significant influence on the electrical conductivity and thermal stability but negligible influence on the yield compared to widely used room temperature polymerization.
引用
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页数:5
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