Polymerization under magnetic field .3. Redox polymerization of acrylonitrile and methyl methacrylate

被引:0
作者
Bag, DS [1 ]
Maiti, S [1 ]
机构
[1] INDIAN INST TECHNOL,CTR MAT SCI,KHARAGPUR 721302,W BENGAL,INDIA
来源
JOURNAL OF POLYMER MATERIALS | 1997年 / 14卷 / 01期
关键词
acrylonitrile; methyl methacrylate; magnetic field (MF); redox polymerization;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The influence of magnetic field (MF) was studied on the polymerization of acrylonitrile (AIV) and methyl methacrylate (MMA) using benzoyl peroxide-dimethylaniline (BPO-DMA) and hydrogen peroxide-thiourea (H2O2-TU) as redox initiators. The effect of MF was observed on the polymerization of AN and not on the MMA. The molecular weight (MW) and density of the polyacrylonitrile (PAN) prepared under MF are higher than that of PAN prepared without MF. The PAN prepared under MF is of narrower molecular weight distribution (MWD) and more thermostable than that prepared without MF.
引用
收藏
页码:25 / 31
页数:7
相关论文
共 50 条
[41]   Polymerization of methyl methacrylate initiated by arylsulfinic acids [J].
Watanabe, T ;
Sakai, K ;
Sato, R ;
Takeishi, M .
POLYMER JOURNAL, 1997, 29 (06) :487-491
[42]   Polymerization of Methyl Methacrylate with α-Diimine Nickel (II) [J].
Zhang Danfeng ;
Li Sen ;
Yu Wen ;
Meng Jiangang .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (07) :1559-1564
[43]   Microemulsion polymerization of methyl methacrylate initiated with BPO [J].
Xu, XL ;
Ge, XW ;
Zhang, ZC ;
Zhang, MW ;
Zuo, J ;
Niu, AZ .
EUROPEAN POLYMER JOURNAL, 1999, 35 (11) :1975-1978
[44]   Modeling of Methyl Methacrylate Polymerization Using MATLAB [J].
Law, Woon Phui ;
Ibrahim, Wan Hanisah Wan ;
Gimbun, Jolius .
CHEMICAL PRODUCT AND PROCESS MODELING, 2016, 11 (03) :185-196
[45]   Kinetics of suspended emulsion polymerization of methyl methacrylate [J].
Bao, YZ ;
Wang, CX ;
Huang, ZM ;
Weng, ZX .
CHINESE JOURNAL OF POLYMER SCIENCE, 2004, 22 (06) :543-548
[46]   Aqueous polymerization of methyl methacrylate initiated by titanium(III)-salicylaldoxime redox system: A kinetic study [J].
Yashoda, MP ;
Sherigara, BS ;
Nayak, PV ;
Venkateswaran, G .
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2000, 37 (11) :1487-1505
[47]   One promising thermoplastic material: Poly(methyl methacrylate) and its continuous glass fiber reinforced composites by redox polymerization [J].
Gao, Yafei ;
Li, Jing ;
Zhang, Chong ;
Zhang, Yiru ;
Liu, Xiaolei ;
Zhou, Lei ;
Yuan, Dongming ;
Zhang, Jianmin .
POLYMER COMPOSITES, 2025, 46 (04) :3030-3041
[48]   STUDIES ON BULK-POLYMERIZATION OF METHYL-METHACRYLATE .1. THERMAL POLYMERIZATION [J].
CLOUET, G ;
CHAUMONT, P ;
CORPART, P .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (11) :2815-2824
[49]   Growth of polymer particles in microemulsion polymerization of methyl methacrylate [J].
Xu, XL ;
Ge, XW ;
Zhang, ZC ;
Zhang, MW ;
Zuo, J ;
Niu, AZ .
ACTA POLYMERICA SINICA, 1998, (06) :658-664
[50]   POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY BENZENESULFINIC ACID [J].
WATANABE, T ;
SAKAI, K ;
OGATA, T ;
TAKEISHI, M .
POLYMER JOURNAL, 1995, 27 (09) :969-973