Liquid-liquid phase transition in Pb-Sn melts

被引:82
作者
Zu, FQ [1 ]
Zhu, ZG
Guo, LJ
Zhang, B
Shui, JP
Liu, CS
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Lab Internal Frict & Defects Solids, Hefei 230031, Peoples R China
[2] Hefei Univ Technol, Dept Mat Sci & Engn, Hefei 230009, Peoples R China
关键词
D O I
10.1103/PhysRevB.64.180203
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A first-order liquid-liquid (LL) phase transition as a function of temperature in Pb-Sn melts is suggested by internal friction experiments and verified by differential thermal analysis with an entropy-driven order-disorder mechanism. It differs remarkably with other already found LL phase transitions in some aspects. The findings may throw light on the nature of viscous liquids in condensed state physics and be of significance in materials science. The present work makes a beneficial attempt at exploring internal friction as an experimental method for studying liquids.
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页数:4
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