Thermal degradation of ABS-Br mixed with PP and catalytic debromination by iron oxide carbon composite catalyst (Fe-C)

被引:24
作者
Bhaskar, T
Murai, K
Brebu, M
Matsui, T
Uddin, MA
Muto, A
Sakata, Y
机构
[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 700, Japan
[2] Petru Poni Inst Macromol Chem, RO-6600 Iasi, Romania
[3] Toda Kogyo Co Ltd, Hiroshima 7390652, Japan
[4] Univ Newcastle, Sch Engn, Proc Safety & Environm Protect Grp, Callaghan, NSW 2308, Australia
关键词
D O I
10.1039/b206487a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The degradation of brominated (Br: 9.59 wt%) flame retardant containing acrylonitrile-butadiene-styrene (ABS) copolymer [waste from electric and electronic equipment, (WEEE)] mixed with polypropylene ( PP) was performed at 450 degreesC using iron oxide carbon composite catalyst (Fe-C) and produced bromine-free liquid products. The majority of nitrogen present in the acrylonitrile portion of ABS-Br was converted into ammonia and also light aliphatic nitriles. The liquid products can be used as a fuel oil or feedstock in the petroleum refinery.
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页码:603 / 606
页数:4
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