Simple and convenient synthetic procedure leading to ruthenium olefin metathesis catalysts bearing the N,N′-bis(mesityl)imidazol-2-ylidene (IMes) ligand

被引：75
|
作者：
Jafarpour, L [1 ]
Nolan, SP [1 ]
机构：
[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 11期
关键词：
D O I：
10.1021/om000203w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The highly active olefin metathesis catalyst precursors RuCl2(=CNR')(IMes)(PR3)(2) (R' = Ph, R = Cy (4), R' = CH=CMe2, R = Cpy (5)) can be conveniently synthesized from their phosphine analogues RuCl2(=CHR')(PR3)(2) (R' = Ph, R = Cy (cyclohexyl) (2), R' = CH=CMe2, R = Cpy (cyclopentyl) (3)), imidazolium salts, and a base by a facile procedure. The ligand exchange reaction is performed in a "one-pot" procedure, and an easy workup leads to good yields of 4 and 5.
引用
收藏
页码：2055 / 2057
页数：3
相关论文
共 9 条
  • [1] Ruthenium carbene complexes with N,N′-bis(mesityl) imidazol-2-ylidene ligands:: RCM catalysts of extended scope
    Fürstner, A
    Thiel, OR
    Ackermann, L
    Schanz, HJ
    Nolan, SP
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (07): : 2204 - 2207
  • [2] Ruthenium olefin metathesis catalysts bearing an N-fluorophenyl-N-mesityl-substituted unsymmetrical N-heterocyclic carbene
    Vougioukalakis, Georgios C.
    Grubbs, Robert H.
    ORGANOMETALLICS, 2007, 26 (09) : 2469 - 2472
  • [3] Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents
    Padunnappattu, Ajay
    Duhayon, Carine
    Cesar, Vincent
    Canac, Yves
    ORGANOMETALLICS, 2022, 41 (20) : 2868 - 2878
  • [4] Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N-Heterocyclic Carbene Ligand: Improved Stability and Activity
    Kosnik, Wioletta
    Lichosyt, Dawid
    Sniezek, Marcin
    Janaszkiewicz, Angelika
    Wozniak, Krzysztof
    Malinska, Maura
    Trzaskowski, Bartosz
    Kajetanowicz, Anna
    Grela, Karol
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (24)
  • [5] Imidazol(in)ium-2-carboxylates as N-heterocyclic carbene precursors in ruthenium-arene catalysts for olefin metathesis and cyclopropanation
    Tudose, Adriana
    Demonceau, Albert
    Delaude, Lionel
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (24-25) : 5356 - 5365
  • [6] Ruthenium Complex Bearing a Hydroxy Group Functionalised N-Heterocyclic Carbene Ligand - A Universal Platform for Synthesis of Tagged and Immobilised Catalysts for Olefin Metathesis
    Monsigny, Louis
    Czarnocki, Stefan
    Sienkiewicz, Michal
    Kopcha, William
    Frankfurter, Rene
    Vogt, Carla
    Solodenko, Wladimir
    Kajetanowicz, Anna
    Kirschning, Andreas
    Grela, Karol
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (46) : 6424 - 6434
  • [7] Ruthenium Complexes Bearing Thiophene-Based Unsymmetrical N-Heterocyclic Carbene Ligands as Selective Catalysts for Olefin Metathesis in Toluene and Environmentally Friendly 2-Methyltetrahydrofuran
    Smolen, Michal
    Kosnik, Wioletta
    Gajda, Roman
    Wozniak, Krzysztof
    Skoczen, Aleksandra
    Kajetanowicz, Anna
    Grela, Karol
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (57) : 15372 - 15379
  • [8] Facile purification of the N-heterocyclic carbene precursor [IMesH][Cl] and chloride binding in the solvates [IMesH][Cl]•acetone and [IMesH][ Cl]•H2O (IMes=1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)
    Cole, ML
    Junk, PC
    CRYSTENGCOMM, 2004, 6 : 173 - 176
  • [9] Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp*(IXy)Ru (IXy=1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium
    Liu, Hsueh-Ju
    Ziegler, Micah S.
    Tilley, T. Don
    POLYHEDRON, 2014, 84 : 203 - 208
1