Simple and convenient synthetic procedure leading to ruthenium olefin metathesis catalysts bearing the N,N′-bis(mesityl)imidazol-2-ylidene (IMes) ligand

被引：75

作者：

Jafarpour, L ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 11期

关键词：

D O I：

10.1021/om000203w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The highly active olefin metathesis catalyst precursors RuCl2(=CNR')(IMes)(PR3)(2) (R' = Ph, R = Cy (4), R' = CH=CMe2, R = Cpy (5)) can be conveniently synthesized from their phosphine analogues RuCl2(=CHR')(PR3)(2) (R' = Ph, R = Cy (cyclohexyl) (2), R' = CH=CMe2, R = Cpy (cyclopentyl) (3)), imidazolium salts, and a base by a facile procedure. The ligand exchange reaction is performed in a "one-pot" procedure, and an easy workup leads to good yields of 4 and 5.

引用

页码：2055 / 2057

页数：3

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