Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with C∧C* Cyclometalating NHC Ligands

被引:17
作者
Pinter, Piermaria [1 ]
Soellner, Johannes [1 ]
Strassner, Thomas [1 ]
机构
[1] Tech Univ Dresden, Phys Organ Chem, D-01069 Dresden, Germany
关键词
Platinum compounds;
D O I
10.1021/acs.organomet.0c00790
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Due to their square-planar geometry, platinum(II) complexes demonstrate an extraordinary and unique photophysical behavior. The photophysical properties of monometallic platinum(II) complexes depend on the concentration, while in bimetallic platinum(II) complexes they depend on the distance between the metal centers. In this study we reveal a correlation between the electronic and photophysical properties of monomeric monometallic platinum(II) complexes and their aggregates with the corresponding bimetallic complexes.
引用
收藏
页码:557 / 563
页数:7
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