A quinoidal bis-phenalenyl-fused porphyrin with supramolecular organization and broad near-infrared absorption

被引：21
|
作者：
Diev, Vyacheslav V. [1 ,2 ]
Femia, Denise [1 ]
Zhong, Qiwen [1 ]
Djurovich, Peter I. [1 ]
Haiges, Ralf [1 ]
Thompson, Mark E. [1 ]
机构：
[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA
[2] EI du Pont Nemours & Co, Expt Stn, Wilmington, DE 19803 USA
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 09期
关键词：
CRYSTAL-STRUCTURE; PHYSICAL-PROPERTIES; IR ABSORPTION; HYDROCARBON; CHEMISTRY;
D O I：
10.1039/c5cc09128d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bis-phenalenyl-fused porphyrin has been synthesized by thermal dehydro-aromatization reaction regioselectively as a single syn-isomer. X-ray crystal structure revealed that both phenalenyl units of this porphyrin have close pi-pi contacts forming continuous network of interacting porphyrin rings. A broad and intense NIR absorption can be attributed to quinoidal character of bis-phenalenyl-fused porphyrin.
引用
收藏
页码：1949 / 1952
页数：4
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