A quinoidal bis-phenalenyl-fused porphyrin with supramolecular organization and broad near-infrared absorption

被引：21

作者：

Diev, Vyacheslav V. ^{[1
,2
]}

Femia, Denise ^{[1
]}

Zhong, Qiwen ^{[1
]}

Djurovich, Peter I. ^{[1
]}

Haiges, Ralf ^{[1
]}

Thompson, Mark E. ^{[1
]}

机构：

[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

[2] EI du Pont Nemours & Co, Expt Stn, Wilmington, DE 19803 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 09期

关键词：

CRYSTAL-STRUCTURE; PHYSICAL-PROPERTIES; IR ABSORPTION; HYDROCARBON; CHEMISTRY;

D O I：

10.1039/c5cc09128d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bis-phenalenyl-fused porphyrin has been synthesized by thermal dehydro-aromatization reaction regioselectively as a single syn-isomer. X-ray crystal structure revealed that both phenalenyl units of this porphyrin have close pi-pi contacts forming continuous network of interacting porphyrin rings. A broad and intense NIR absorption can be attributed to quinoidal character of bis-phenalenyl-fused porphyrin.

引用

页码：1949 / 1952

页数：4

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