Syntheses, topological structures and physical properties of two 2D lanthanide-organic frameworks constructed from 5-nitroisophthalic acid

被引：12
作者：
Lin, Jian-Di [1 ,2 ]
Lin, Mei-Zhen [3 ]
Tian, Chong-Bin [1 ,2 ]
Lin, Ping [1 ]
Du, Shao-Wu [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
[3] Fujian Agr & Forestry Univ, Coll Plant Protect, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 938卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; Lanthanide MOFs; Crystal structures; Topological analyses; Photoluminescent; Magnetic properties; METAL COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SHAPE-SELECTIVITY; COMPLEXES; CATALYSTS; LIGAND; SERIES; MOFS; ND;
D O I：
10.1016/j.molstruc.2009.09.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two lanthanide-organic frameworks Pr-2[(NIPH)(3)center dot 3H(2)O] H2O (1) and [Nd-2(NIPH)(3)center dot 3H2O]H2O (2) were synthesized via the self-assembly of Ln(NO3)center dot 6H(2)O (Ln = Pr or Nd) with 5-nitroisophthalic acid (H2NIPH) in the presence of imidazole under hydrothermal reactions. X-ray single-crystal diffraction analyses reveal that 1 and 2 are isomorphic and both exhibit an unprecedented 2D topological net. Compounds 1 and 2 both have a 3D supramolecular framework extended by hydrogen-bonding interactions between the adjacent layers. Furthermore. the magnetic behaviors for 1 and 2 in the temperature range of 2-300 K were investigated. (C) 2009 Elsevier B.V. All rights reserved
引用
收藏
页码：111 / 116
页数：6
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