Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide

被引：3

作者：

Abushakhmina, GM

Khalizov, AF

Zlotskii, SS

Shereshovets, VV

Imashev, UB

机构：

[1] RAS, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Russia

[2] Ufa State Oil Tech Univ, Ufa 450062, Russia

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 70卷 / 01期

关键词：

chlorine dioxide; dioxolanes; free radicals; reaction kinetics;

D O I：

10.1023/A:1010391405815

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chlorine dioxide oxidizes readily 2-isopropyl-1,3-dioxolane (1) in CH2Cl2, affording 2-hydroxyethyl isobutyrate. When the reaction is carried out in CHCl3 or CCl4, an additional product, 2-chloroethyl isobutyrate, forms in a comparable yield. Kinetics of the reaction follows a second order law -d[ClO2]/dt = k [ClO2][1] with the rate constant 1gk = (9.0 +/- 1.9)-(17.3 +/- 2.6)/theta [L/(mol s)], theta = 2.303 RT kcal/mol.

引用

页码：177 / 182

页数：6

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