Nanowindow-induced molecular sieving effect in a single-wall carbon nanohorn

被引：76
作者：
Murata, K
Hirahara, K
Yudasaka, M
Iijima, S
Kasuya, D
Kaneko, K
机构：
[1] Chiba Univ, Grad Sch Nat Sci & Technol, Inage Ku, Chiba 2638522, Japan
[2] Chiba Univ, Ctr Frontier Elect & Photon, Chiba 2638522, Japan
[3] Meijo Univ, Fac Sci & Technol, Dept Mat Sci & Technol, Tenpa Ku, Nagoya, Aichi 4688502, Japan
[4] NEC Corp Ltd, Japan Sci & Technol Corp, Tsukuba, Ibaraki 3058501, Japan
[5] Meijo Univ, Dept Phys, Tenpa Ku, Nagoya, Aichi 4688502, Japan
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 49期
关键词：
D O I：
10.1021/jp026909g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Subnanoscale windows (nanowindows) were donated to the walls of single-wall carbon nanohorns (SWNHs) by oxidation in oxygen at different temperatures of 573-693 K. We determined the accessibility of internal nanospaces of the SWNHs through nanowindows to He, Ar, N-2, CH4, SF6, and C-60. An explicit molecular sieving effect of SWNHs due to the nanowindow was shown.
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页码：12668 / 12669
页数：2
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