A new 2D HgII coordination polymer containing novel coordination mode of 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (bpo) ligand, [Hg(μ-bpo)2- (N3)2]n:: Spectroscopic, thermal, fluorescence and structural studies

A new two-dimensional Hg-II coordination polymer containing 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (bpo) and azide anions, [Hg(mu-bpo)(2)(N-3)(2)](n), has been synthesized and characterized by elemental analysis, IR-, H-1 NMR-, C-13 NMR spectroscopy and structurally determined by X-ray single-crystal diffraction. The thermal stability of compound [Hg(mu-bpo)(2)(N-3)(2)](n) was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The single-crystal X-ray data shows that ligand bpo is bridged via one pyridyl nitrogen and one oxadiazole nitrogen atom, as a novel coordination mode of the ligand bpo. Furthermore, the ligand and complex are luminescent lin the solid state, with emission maxima in the visible light region (lambda(max) = 470 nm for both bpo and [Hg(mu-bpo)(2)(N-3)(2)](n)). (c) 2006 Elsevier B.V. All rights reserved.