Heterogeneous Heck reaction catalysed by silica gel-supported 1,2-diaminocyclohexane-Pd complex

被引：16

作者：

Alam, Md. Nazmul ^{[1
]}

Sarkar, Shaheen M. ^{[2
]}

Miah, Md. Rezwan ^{[1
]}

机构：

[1] Shahjalal Univ Sci & Technol, Dept Chem, Sch Phys Sci, Sylhet 3114, Bangladesh

[2] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2009年 / 98卷 / 02期

关键词：

Heck reaction; Heterogeneous Pd catalysis; 1,2-Diaminocyclohexane; CROSS-COUPLING REACTIONS; RECOVERABLE CATALYST; PALLADIUM CATALYSTS; SUZUKI-MIYAURA; EFFICIENT; SONOGASHIRA;

D O I：

10.1007/s11144-009-0085-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A 1,2-diaminocyclohexane-Pd complex was immobilized onto the surface of silica gel and investigated as a catalyst for Heck coupling reactions. The immobilized catalyst exhibited high catalytic activity in the coupling of activated and nonactivated aryl substrates with various acrylates. Moreover, the catalyst was air-stable that could be recycled and reused without significant loss of catalytic activity.

引用

页码：383 / 389

页数：7

共 16 条

[1] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[2] Palladium metal catalysts in Heck C-C coupling reactions [J].

Biffis, A ;

Zecca, M ;

Basato, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) :249-274

[3] A highly active catalyst for Suzuki-Miyaura cross-coupling reactions of heteroaryl compounds [J].

Billingsley, Kelvin L. ;

Anderson, Kevin W. ;

Buchwald, Stephen L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (21) :3484-3488

[4] Efficient palladium-catalyzed Heck reactions mediated by the diol-functionalized imidazolium ionic liquids [J].

Cai, Yueqin ;

Liu, Ye .

CATALYSIS COMMUNICATIONS, 2009, 10 (10) :1390-1393

[5] Di(2-pyridyl)methylamine-palladium dichloride complex covalently anchored to a styrene-maleic anhydride co-polymer as recoverable catalyst for C-C cross-coupling reactions in water [J].

Gil-Moltó, J ;

Karlström, S ;

Nájera, C .

TETRAHEDRON, 2005, 61 (51) :12168-12176

[6] PALLADACYCLES AS STRUCTURALLY DEFINED CATALYSTS FOR THE HECK OLEFINATION OF CHLOROARENES AND BROMOARENES [J].

HERRMANN, WA ;

BROSSMER, C ;

OFELE, K ;

REISINGER, CP ;

PRIERMEIER, T ;

BELLER, M ;

FISCHER, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1844-1848

[7] New N-heterocyclic carbene palladium complex/ionic liquid matrix immobilized on silica: Application as recoverable catalyst for the Heck reaction [J].

Karimi, B ;

Enders, D .

ORGANIC LETTERS, 2006, 8 (06) :1237-1240

[8] Biphenyl-based phosphine: A well-defined, air-stable, and efficient ligand for the Mizoroki-Heck reaction [J].

Nadri, Shirin ;

Joshaghani, Mohammad ;

Rafiee, Ezzat .

APPLIED CATALYSIS A-GENERAL, 2009, 362 (1-2) :163-168

[9]

OH M, 1999, CHEM COMMUN, P357

[10] Palladium containing nanostructured silica functionalized with pyridine sites: a versatile heterogeneous catalyst for Heck, Sonogashira, and cyanation reactions [J].

Polshettiwar, Vivek ;

Hesemann, Peter ;

Moreau, Joel J. E. .

TETRAHEDRON, 2007, 63 (29) :6784-6790

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