Thermodynamic analysis of Si doping in GaN

被引:2
作者
Halidou, I. [1 ]
Benzarti, Z. [1 ]
Boufaden, T. [1 ]
El Jani, B. [1 ]
机构
[1] Fac Sci, URHEA, Monastir 5000, Tunisia
关键词
thermodynamic calculations; MOVPE; GaN; Si doping; VAPOR-PHASE EPITAXY; GROWTH-RATE REDUCTION; SAPPHIRE SUBSTRATE; BUFFER LAYER; THIN-FILMS; DOPED GAN; MOVPE; ALXGA1-XN; GAAS;
D O I
10.1016/j.spmi.2006.09.023
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Equilibrium calculations of Si-doping in GaN are investigated using the Gemini code. The method of the calculation is based on the minimisation of the Gibbs free energy. Experimental growth conditions are used for the calculation. The variables are the amount of the dopant and the temperature. The results show the formation of a solid Si3N4 compound with a certain quantity of the input SiH4, that is the silicon precursor in our MOVPE system. Si3N4 formation can explain the limitation of Si incorporation and the surface roughening as revealed by MOVPE Si doped layers. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:496 / 500
页数:5
相关论文
共 23 条
[1]  
[Anonymous], 1971, 37 NSRDSNBS
[2]   Thermodynamic analysis of growth rate reduction by VCl4 during metalorganic vapor-phase epitaxy of GaAs [J].
Bchetnia, A ;
Rebey, A ;
Boufaden, T ;
El Jani, B .
JOURNAL OF CRYSTAL GROWTH, 1999, 207 (1-2) :15-19
[3]   Silicon effect on GaN surface morphology [J].
Benzarti, Z ;
Halidou, I ;
Tottereau, O ;
Boufaden, T ;
El Jani, B .
MICROELECTRONICS JOURNAL, 2002, 33 (11) :995-998
[4]   The role of the growth temperature for the SiN interlayer deposition in GaN [J].
Böttcher, T ;
Dennemarck, J ;
Kröger, R ;
Figge, S ;
Hommel, D .
5TH INTERNATIONAL CONFERENCE ON NITRIDE SEMICONDUCTORS (ICNS-5), PROCEEDINGS, 2003, 0 (07) :2039-2042
[5]  
CHEYNET B, THERMODATA INPG CNRS
[6]  
Frayssinet E, 2002, MRS INTERNET J N S R, V7
[7]   Heavily silicon-doped GaN by MOVPE [J].
Halidou, I ;
Benzarti, Z ;
Chine, Z ;
Boufaden, T ;
El Jani, B .
MICROELECTRONICS JOURNAL, 2001, 32 (02) :137-142
[8]   DOPING OF GALLIUM-ARSENIDE IN MOCVD - EQUILIBRIUM CALCULATIONS [J].
KEIZER, LC ;
TANG, X ;
VANMEERTEN, RZC ;
GILING, LJ .
JOURNAL OF CRYSTAL GROWTH, 1990, 102 (03) :667-677
[9]   DOPING OF GAN WITH SI AND PROPERTIES OF BLUE M/I/N/N+ GAN LED WITH SI-DOPED N+-LAYER BY MOVPE [J].
KOIDE, N ;
KATO, H ;
SASSA, M ;
YAMASAKI, S ;
MANABE, K ;
HASHIMOTO, M ;
AMANO, H ;
HIRAMATSU, K ;
AKASAKI, I .
JOURNAL OF CRYSTAL GROWTH, 1991, 115 (1-4) :639-642
[10]   Thermodynamic analysis of the MOVPE growth of InGaAlN quaternary alloy [J].
Koukitu, A ;
Kumagai, Y ;
Seki, H .
JOURNAL OF CRYSTAL GROWTH, 2000, 221 :743-750