Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C-O Bond Activation

被引：183

作者：

Li, Bi-Jie ^{[1
,2
,3
]}

Xu, Li ^{[1
,2
,3
,4
]}

Wu, Zhen-Hua ^{[1
,2
,3
]}

Guan, Bing-Tao ^{[1
,2
,3
]}

Sun, Chang-Liang ^{[1
,2
,3
]}

Wang, Bi-Qin ^{[4
]}

Shi, Zhang-Jie ^{[1
,2
,3
,5
]}

机构：

[1] Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China

[2] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China

[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China

[4] Sichuan Normal Univ, Dept Chem, Chengdu 610068, Sichuan, Peoples R China

[5] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期

关键词：

ALKYL-HALIDES; BETA-HYDROGENS; IRON CATALYSIS; ARYL CHLORIDES;

D O I：

10.1021/ja907281f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylate electrophile and an iron catalyst would generate ample advantages.

引用

页码：14656 / +

页数：3

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