Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C-O Bond Activation

被引：183
作者：
Li, Bi-Jie [1 ,2 ,3 ]
Xu, Li [1 ,2 ,3 ,4 ]
Wu, Zhen-Hua [1 ,2 ,3 ]
Guan, Bing-Tao [1 ,2 ,3 ]
Sun, Chang-Liang [1 ,2 ,3 ]
Wang, Bi-Qin [4 ]
Shi, Zhang-Jie [1 ,2 ,3 ,5 ]
机构：
[1] Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China
[2] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China
[4] Sichuan Normal Univ, Dept Chem, Chengdu 610068, Sichuan, Peoples R China
[5] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期
关键词：
ALKYL-HALIDES; BETA-HYDROGENS; IRON CATALYSIS; ARYL CHLORIDES;
D O I：
10.1021/ja907281f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylate electrophile and an iron catalyst would generate ample advantages.
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收藏
页码：14656 / +
页数：3
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